In thermodynamics, the thermal efficiency is a dimensionless performance measure of
a device that uses thermal energy, such as an internal combustion engine, a steam turbine
or a steam engine, a boiler, a furnace, or a refrigerator for example. In other words,
efficiency indicates how well an energy conversion or transfer process is accomplished.
Overview
In general, energy conversion efficiency is the ratio between the useful output of a device
and the input, in energy terms. For thermal efficiency, the input, , to the device is
heat, or the heat-content of a fuel that is consumed. The desired output is mechanical
work, , or heat, , or possibly both. Because the input heat normally has a real financial
cost, a memorable, generic definition of thermal efficiency is
From the first law of thermodynamics, the energy output cannot exceed the input, so
When expressed as a percentage, the thermal efficiency must be between 0% and 100%. Efficiency
is typically less than 100% because there are inefficiencies such as friction and heat
loss that convert the energy into alternative forms. For example, a typical gasoline automobile
engine operates at around 25% efficiency, and a large coal-fueled electrical generating
plant peaks at about 46%. The largest diesel engine in the world peaks at 51.7%. In a combined
cycle plant, thermal efficiencies are approaching 60%. Such a real-world value may be used as
a figure of merit for the device. For engines where a fuel is burned there are
two types of thermal efficiency: indicated thermal efficiency and brake thermal efficiency.
This efficiency is only appropriate when comparing similar types or similar devices.
For other systems the specifics of the calculations of efficiency vary but the non dimensional
input is still the same. Efficiency = Output energy / input energy
Heat engines Heat engines transform thermal energy, or
heat, Qin into mechanical energy, or work, Wout. They cannot do this task perfectly,
so some of the input heat energy is not converted into work, but is dissipated as waste heat
Qout into the environment
The thermal efficiency of a heat engine is the percentage of heat energy that is transformed
into work. Thermal efficiency is defined as
The efficiency of even the best heat engines is low; usually below 50% and often far below.
So the energy lost to the environment by heat engines is a major waste of energy resources,
although modern cogeneration, combined cycle and energy recycling schemes are beginning
to use this heat for other purposes. Since a large fraction of the fuels produced worldwide
go to powering heat engines, perhaps up to half of the useful energy produced worldwide
is wasted in engine inefficiency. This inefficiency can be attributed to three causes. There is
an overall theoretical limit to the efficiency of any heat engine due to temperature, called
the Carnot efficiency. Second, specific types of engines have lower limits on their efficiency
due to the inherent irreversibility of the engine cycle they use. Thirdly, the nonideal
behavior of real engines, such as mechanical friction and losses in the combustion process
causes further efficiency losses. Carnot efficiency
The second law of thermodynamics puts a fundamental limit on the thermal efficiency of all heat
engines. Even an ideal, frictionless engine can't convert anywhere near 100% of its input
heat into work. The limiting factors are the temperature at which the heat enters the engine,
, and the temperature of the environment into which the engine exhausts its waste heat,
, measured in an absolute scale, such as the Kelvin or Rankine scale. From Carnot's theorem,
for any engine working between these two temperatures:
This limiting value is called the Carnot cycle efficiency because it is the efficiency of
an unattainable, ideal, reversible engine cycle called the Carnot cycle. No device converting
heat into mechanical energy, regardless of its construction, can exceed this efficiency.
Examples of are the temperature of hot steam entering the turbine of a steam power plant,
or the temperature at which the fuel burns in an internal combustion engine. is usually
the ambient temperature where the engine is located, or the temperature of a lake or river
that waste heat is discharged into. For example, if an automobile engine burns gasoline at
a temperature of and the ambient temperature is , then its maximum possible efficiency
is:
It can be seen that since is fixed by the environment, the only way for a designer to
increase the Carnot efficiency of an engine is to increase , the temperature at which
the heat is added to the engine. The efficiency of ordinary heat engines also generally increases
with operating temperature, and advanced structural materials that allow engines to operate at
higher temperatures is an active area of research. Due to the other causes detailed below, practical
engines have efficiencies far below the Carnot limit. For example, the average automobile
engine is less than 35% efficient. Carnot's theorem applies to thermodynamic
cycles, where thermal energy is converted to mechanical work. Devices that convert a
fuel's chemical energy directly into electrical work, such as fuel cells, can exceed the Carnot
efficiency. Engine cycle efficiency
The Carnot cycle is reversible and thus represents the upper limit on efficiency of an engine
cycle. Practical engine cycles are irreversible and thus have inherently lower efficiency
than the Carnot efficiency when operated between the same temperatures and . One of the factors
determining efficiency is how heat is added to the working fluid in the cycle, and how
it is removed. The Carnot cycle achieves maximum efficiency because all the heat is added to
the working fluid at the maximum temperature , and removed at the minimum temperature . In
contrast, in an internal combustion engine, the temperature of the fuel-air mixture in
the cylinder is nowhere near its peak temperature as the fuel starts to burn, and only reaches
the peak temperature as all the fuel is consumed, so the average temperature at which heat is
added is lower, reducing efficiency. An important parameter in the efficiency of
combustion engines is the specific heat ratio of the air-fuel mixture, γ. This varies somewhat
with the fuel, but is generally close to the air value of 1.4. This standard value is usually
used in the engine cycle equations below, and when this approximation is made the cycle
is called an air-standard cycle. Otto cycle: automobiles The Otto cycle is
the name for the cycle used in spark-ignition internal combustion engines such as gasoline
and hydrogen fueled automobile engines. Its theoretical efficiency depends on the compression
ratio r of the engine and the specific heat ratio γ of the gas in the combustion chamber.
Thus, the efficiency increases with the compression ratio. However the compression ratio of Otto
cycle engines is limited by the need to prevent the uncontrolled combustion known as knocking.
Modern engines have compression ratios in the range 8 to 11, resulting in ideal cycle
efficiencies of 56% to 61%. Diesel cycle: trucks and trains In the Diesel
cycle used in diesel truck and train engines, the fuel is ignited by compression in the
cylinder. The efficiency of the Diesel cycle is dependent on r and γ like the Otto cycle,
and also by the cutoff ratio, rc, which is the ratio of the cylinder volume at the beginning
and end of the combustion process:
The Diesel cycle is less efficient than the Otto cycle when using the same compression
ratio. However, practical Diesel engines are 30% - 35% more efficient than gasoline engines.
This is because, since the fuel is not introduced to the combustion chamber until it is required
for ignition, the compression ratio is not limited by the need to avoid knocking, so
higher ratios are used than in spark ignition engines.
Rankine cycle: steam power plants The Rankine cycle is the cycle used in steam turbine power
plants. The overwhelming majority of the world's electric power is produced with this cycle.
Since the cycle's working fluid, water, changes from liquid to vapor and back during the cycle,
their efficiencies depend on the thermodynamic properties of water. The thermal efficiency
of modern steam turbine plants with reheat cycles can reach 47%, and in combined cycle
plants, in which a steam turbine is powered by exhaust heat from a gas turbine, it can
approach 60%. Brayton cycle: gas turbines and jet engines
The Brayton cycle is the cycle used in gas turbines and jet engines. It consists of a
compressor that increases pressure of the incoming air, then fuel is continuously added
to the flow and burned, and the hot exhaust gasses are expanded in a turbine. The efficiency
depends largely on the ratio of the pressure inside the combustion chamber p2 to the pressure
outside p1
Other inefficiencies The above efficiency formulas are based on
simple idealized mathematical models of engines, with no friction and working fluids that obey
simple thermodynamic rules called the ideal gas law. Real engines have many departures
from ideal behavior that waste energy, reducing actual efficiencies far below the theoretical
values given above. Examples are: friction of moving parts
inefficient combustion heat loss from the combustion chamber
departure of the working fluid from the thermodynamic properties of an ideal gas
aerodynamic drag of air moving through the engine
energy used by auxiliary equipment like oil and water pumps
inefficient compressors and turbines imperfect valve timing
Another source of inefficiency is that engines must be optimized for other goals besides
efficiency, such as low pollution. The requirements for vehicle engines are particularly stringent:
they must be designed for low emissions, adequate acceleration, fast starting, light weight,
low noise, etc. These require compromises in design that reduce efficiency. The average
automobile engine is only about 35% efficient, and must also be kept idling at stoplights,
wasting an additional 17% of the energy, resulting in an overall efficiency of 18%. Large stationary
electric generating plants have fewer of these competing requirements as well as more efficient
Rankine cycles, so they are significantly more efficient than vehicle engines, around
50% Therefore, replacing internal combustion vehicles with electric vehicles, which run
on a battery that is charged with electricity generated by burning fuel in a power plant,
has the theoretical potential to increase the thermal efficiency of energy use in transportation,
thus decreasing the demand for fossil fuels. When comparing different heat engines as sources
of power, such as electric power or the power to run vehicles, the engine efficiency alone
is only one factor. To give a meaningful comparison, the overall efficiency of the entire energy
supply chain from the fuel source to the consumer must be considered. Although the heat wasted
by heat engines is usually the largest source of inefficiency, factors such as the energy
cost of fuel refining and transportation, and energy loss in electrical transmission
lines to transport it, may offset the advantage of a more efficient heat engine.
Energy conversion For a device that converts energy from another
form into thermal energy, the thermal efficiency is
where the quantities are heat-equivalent values. So, for a boiler that produces 210 kW output
for each 300 kW heat-equivalent input, its thermal efficiency is 210/300 = 0.70, or 70%.
This means that 30% of the energy is lost to the environment.
An electric resistance heater has a thermal efficiency close to 100%. When comparing heating
units, such as a highly efficient electric resistance heater to an 80% efficient natural
gas-fueled furnace, an economic analysis is needed to determine the most cost-effective
choice. Effects of fuel heating value
The heating value of a fuel is the amount of heat released during an exothermic reaction
and is a characteristic of each substance. It is measured in units of energy per unit
of the substance, usually mass, such as: kJ/kg, J/mol.
The heating value for fuels is expressed as the HHV, LHV, or GHV to distinguish treatment
of the heat of phase changes: Higher heating value is determined by bringing
all the products of combustion back to the original pre-combustion temperature, and in
particular condensing any vapor produced. This is the same as the thermodynamic heat
of combustion. Lower heating value is determined by subtracting
the heat of vaporization of the water vapor from the higher heating value. The energy
required to vaporize the water therefore is not realized as heat.
Gross heating value accounts for water in the exhaust leaving as vapor, and includes
liquid water in the fuel prior to combustion. This value is important for fuels like wood
or coal, which will usually contain some amount of water prior to burning.
Which definition of heating value is being used significantly affects any quoted efficiency.
Not stating whether an efficiency is HHV or LHV renders such numbers very misleading.
Heat pumps and refrigerators Heat pumps, refrigerators and air conditioners
use work to move heat from a colder to a warmer place, so their function is the opposite of
a heat engine. The work energy that is applied to them is converted into heat, and the sum
of this energy and the heat energy that is moved from the cold reservoir is equal to
the total heat energy added to the hot reservoir
Their efficiency is measured by a coefficient of performance. Heat pumps are measured by
the efficiency with which they add heat to the hot reservoir, COPheating; refrigerators
and air conditioners by the efficiency with which they remove heat from the cold interior,
COPcooling:
The reason for not using the term 'efficiency' is that the coefficient of performance can
often be greater than 100%. Since these devices are moving heat, not creating it, the amount
of heat they move can be greater than the input work. Therefore, heat pumps can be a
more efficient way of heating than simply converting the input work into heat, as in
an electric heater or furnace. Since they are heat engines, these devices
are also limited by Carnot's theorem. The limiting value of the Carnot 'efficiency'
for these processes, with the equality theoretically achievable only with an ideal 'reversible'
cycle, is:
The same device used between the same temperatures is more efficient when considered as a heat
pump than when considered as a refrigerator:
This is because when heating, the work used to run the device is converted to heat and
adds to the desired effect, whereas if the desired effect is cooling the heat resulting
from the input work is just an unwanted byproduct. Energy efficiency
The 'thermal efficiency' is sometimes called the energy efficiency. In the United States,
in everyday usage the SEER is the more common measure of energy efficiency for cooling devices,
as well as for heat pumps when in their heating mode. For energy-conversion heating devices
their peak steady-state thermal efficiency is often stated, e.g., 'this furnace is 90%
efficient', but a more detailed measure of seasonal energy effectiveness is the Annual
Fuel Utilization Efficiency. Energy Efficiency of heat exchangers
A counter flow heat exchanger is generally 100% efficient in transferring heat energy
from one circuit to the other, albeit at a slight loss in temperature. However, for a
more complete picture of heat exchanger efficiency, exergetic considerations must be taken into
account. See also
Kalina cycle Electrical efficiency
Mechanical efficiency Heat engine
Federal Roofing Tax Credit for Energy Efficiency Figure of merit
Heat of combustion Lower heating value
Relative cost of electricity generated by different sources
Higher heating value Energy conversion efficiency
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by Howell and Buckius, McGraw-Hill, New York, 1987
^ GE Power’s H Series Turbine ^ The Internal Combustion Engine in Theory
and Practice: Vol. 1 - 2nd Edition, Revised, MIT Press, 1985, Charles Fayette Taylor - Equation
1-4, page 9 ^ a b c d e Holman, Jack P.. Thermodynamics.
New York: McGraw-Hill. p. 217. ISBN 0-07-029625-1. ^ Sharma, B. K.. Electro Chemistry, 5th Ed..
Krishna Prakashan Media. pp. E–213. ISBN 8185842965. ^ Winterbone, D.; Ali Turan. Advanced Thermodynamics
for Engineers. Butterworth-Heinemann. p. 345. ISBN 0080523366.
^ a b "Where does the energy go?". Advanced technologies and energy efficiency, Fuel Economy
Guide. US Dept. of Energy. 2009. Retrieved 2009-12-02.
^ http:www.energysavers.govspace_heating_coolingmytopic=12520 ^ HVAC Systems and Equipment volume of the
ASHRAE Handbook, ASHRAE, Inc., Atlanta, GA, USA, 2004